Issue 17, 2011

Titanium alkoxyimido (Ti[double bond, length as m-dash]N–OR) complexes: reductive N–O bond cleavage at the boundary between hydrazide and peroxide ligands

Abstract

The first Group 4 alkoxyimido compounds are reported. The Ti[double bond, length as m-dash]N–OtBu group in Ti(N2NMe)(NOtBu)(py) undergoes facile 2-electron N–O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene groupvia two highly selective N–C bond forming events.

Graphical abstract: Titanium alkoxyimido (Ti [[double bond, length as m-dash]] N–OR) complexes: reductive N–O bond cleavage at the boundary between hydrazide and peroxide ligands

Supplementary files

Article information

Article type
Communication
Submitted
14 Feb 2011
Accepted
14 Mar 2011
First published
28 Mar 2011

Chem. Commun., 2011,47, 4926-4928

Titanium alkoxyimido (Ti[double bond, length as m-dash]N–OR) complexes: reductive N–O bond cleavage at the boundary between hydrazide and peroxide ligands

A. D. Schwarz, A. Nova, E. Clot and P. Mountford, Chem. Commun., 2011, 47, 4926 DOI: 10.1039/C1CC10862J

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