Issue 20, 2010
From the journal:

Chemical Communications

Both [2+2] and [2+4] additions of inert aromatics via identical ternary host–guest complexes†

Shinnosuke Horiuchi,a   Yuki Nishioka,a   Takashi Murasea  and  Makoto Fujita*a  

* Corresponding authors

a Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: mfujita@appchem.t.u-tokyo.ac.jp
Fax: +81 3-5841-7257
Tel: +81 3-5841-7258

Abstract

A self-assembled coordination cage enables inert aromatics to undergo both [2+2] and [2+4] cycloadditions by encapsulating them within the cavity. Aceanthrylene reacts with a maleimide derivative under thermal and photo-irradiation conditions to give a product as a single regio- and stereoisomer.

Graphical abstract: Both [2+2] and [2+4] additions of inert aromatics via identical ternary host–guest complexes

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Article information

DOI
https://doi.org/10.1039/C003191G
Article type
Communication
Submitted
15 Feb 2010
Accepted
17 Apr 2010
First published
22 Apr 2010

Chem. Commun., 2010,46, 3460-3462

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Both [2+2] and [2+4] additions of inert aromatics via identical ternary host–guest complexes

S. Horiuchi, Y. Nishioka, T. Murase and M. Fujita, Chem. Commun., 2010, 46, 3460 DOI: 10.1039/C003191G

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