The addition product of styrene, bromine, and dimethyl sulphide was treated with bases to give the dimethyl-α-styrylsulphonium ion which reacted rapidly with various nucleophiles and also underwent slower base-catalysed rearrangement.
Y. L. Chow, B. H. Bakker and K. Iwai, J. Chem. Soc., Chem. Commun., 1980, 521 DOI: 10.1039/C39800000521
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