The vibrational spectra of the acetylene ligand in [Os3(CO)9(µ2-CO)(µ-η2-C2H2)] and the identification of a similar species from acetylene adsorbed on Pt(111) and Pd(111)

Christopher E. Anson; Bernard T. Keiller; Ian A. Oxton; Donald B. Powell; Norman Sheppard

doi:10.1039/C39830000470

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The vibrational spectra of the acetylene ligand in [Os₃(CO)₉(µ₂-CO)(µ-η²-C₂H₂)] and the identification of a similar species from acetylene adsorbed on Pt(111) and Pd(111)

Christopher E. Anson, Bernard T. Keiller, Ian A. Oxton, Donald B. Powell and Norman Sheppard

Abstract

The i.r. and Raman spectra of the acetylenic ligand in [Os₃(CO)₉(µ₂-CO)(µ₃-η²-C₂H₂)] have been analysed and close analogies with electron energy loss spectra obtained from acetylene chemisorbed on Pt(111) and Pd(111) crystal faces confirm that the adsorbed species have the same hydrocarbon structure as the ligand.

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DOI: https://doi.org/10.1039/C39830000470
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1983, 470-472

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The vibrational spectra of the acetylene ligand in [Os₃(CO)₉(µ₂-CO)(µ-η²-C₂H₂)] and the identification of a similar species from acetylene adsorbed on Pt(111) and Pd(111)

C. E. Anson, B. T. Keiller, I. A. Oxton, D. B. Powell and N. Sheppard, J. Chem. Soc., Chem. Commun., 1983, 470 DOI: 10.1039/C39830000470

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Journal of the Chemical Society, Chemical Communications

The vibrational spectra of the acetylene ligand in [Os₃(CO)₉(µ₂-CO)(µ-η²-C₂H₂)] and the identification of a similar species from acetylene adsorbed on Pt(111) and Pd(111)

Abstract

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The vibrational spectra of the acetylene ligand in [Os₃(CO)₉(µ₂-CO)(µ-η²-C₂H₂)] and the identification of a similar species from acetylene adsorbed on Pt(111) and Pd(111)

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