Meso-tetra(2,6-dichlorophenyl)porphinatoiron(III)chloride and meso-tetra(pentachlorophenyl)porphinatioiron(III)chloride, which resist µ-oxo dimmer formation and oxidative destruction, are found to be unusually efficient catalysts for high-turnover, high-yield alkene epoxidation and alkane hydroxylation.
P. S. Traylor, D. Dolphin and T. G. Traylor, J. Chem. Soc., Chem. Commun., 1984, 279 DOI: 10.1039/C39840000279
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