SCHEDULED MAINTENANCE
Synthesis of (dppe)Pt(OMe)2(1)[dppe = 1,2-bis(diphenylphosphino)ethane] by NaOMe metathesis on the analogous dichloride is reported along with the thermal and carbonylation chemistry of (1); the release of dimethyl carbonate and dimethyl oxalate from the carbonylation product (dppe)Pt(CO2Me)2 was accomplished by thermal and oxidative techniques.
H. E. Bryndza, S. A. Kretchmar and T. H. Tulip, J. Chem. Soc., Chem. Commun., 1985, 977 DOI: 10.1039/C39850000977
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