SCHEDULED MAINTENANCE
For SN2 reactions of the type Y–+ MeX → YMe + X–, there exist extended linear correlations between (i) the magnitude of the central barrier and the percentage elongation of the C–X bond in the transition state; (ii) the looseness of the transition state and the sum of the forward and reverse central barriers.
S. S. Shaik, H. B. Schlegel and S. Wolfe, J. Chem. Soc., Chem. Commun., 1988, 1322 DOI: 10.1039/C39880001322
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