Issue 24, 1991

Nucleophilic attack at the meso position of a uranyl sapphyrin complex

Abstract

Contrary to previous reports sapphyrin does react with uranyl cation to give a stable complex, which is no longer aromatic, having undergone attack by methoxide to give a new neutral complex; the synthesis, characterisation and X-ray structure of the new compound are described.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1710-1713

Nucleophilic attack at the meso position of a uranyl sapphyrin complex

A. K. Burrell, M. J. Cyr, V. Lynch and J. L. Sessler, J. Chem. Soc., Chem. Commun., 1991, 1710 DOI: 10.1039/C39910001710

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