Issue 24, 1995

Switching of two amine ligands via an SN2-type mechanism in a coordinated form of 2,6-bis(N,N-dimethylaminomethyl)phenylboronates

Abstract

Facile exchange between the intramoleculariy coordinated and uncoordinated amine ligands in the title compounds is evidenced by NMR spectroscopy in solution, whereas the dynamic process is frozen in the solid phase as shown by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 2499-2500

Switching of two amine ligands via an SN2-type mechanism in a coordinated form of 2,6-bis(N,N-dimethylaminomethyl)phenylboronates

S. Toyota, T. Futawaka, H. Ikeda and M. Ōki, J. Chem. Soc., Chem. Commun., 1995, 2499 DOI: 10.1039/C39950002499

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