SCHEDULED MAINTENANCE
Pentacarbonyl[(+)- and (–)-menthyloxycarbene] complexes of chromium react with 3, 3-dimethylbut-1-yne diastereoselectively to give optically active naphthalene–Cr(CO)3 complexes which upon warming undergo an intramolecular haptotropic migration of the metal fragment.
K. H. Dötz, C. Stinner and M. Nieger, J. Chem. Soc., Chem. Commun., 1995, 2535 DOI: 10.1039/C39950002535
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