Issue 45, 2014
From the journal:

Chemical Communications

A gold-catalysed fully intermolecular oxidation and sulfur-ylide formation sequence on ynamides†

Mickaël Dos Santosa  and  Paul W. Davies*a  

* Corresponding authors

a School of Chemistry, University of Birmingham, Edgbaston, Birmingham, UK
E-mail: p.w.davies@bham.ac.uk
Tel: +44 (0)121 4144408

Abstract

An efficient C–O, C–S and C–C bond-forming sequence leads to functionalised compounds bearing sulfur-substituted quaternary carbons. Ynamides are employed as diazo-equivalents to access the [2,3]-sigmatropic rearrangements of allyl sulfonium ylides by a three-component chemoselective oxidation and intermolecular ylide formation.

Graphical abstract: A gold-catalysed fully intermolecular oxidation and sulfur-ylide formation sequence on ynamides

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Article information

DOI
https://doi.org/10.1039/C4CC01059K
Article type
Communication
Submitted
10 Feb 2014
Accepted
16 Apr 2014
First published
16 Apr 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 6001-6004

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A gold-catalysed fully intermolecular oxidation and sulfur-ylide formation sequence on ynamides

M. D. Santos and P. W. Davies, Chem. Commun., 2014, 50, 6001 DOI: 10.1039/C4CC01059K

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