Issue 17, 2015

From competition to cooperation: a highly efficient strategy towards well-defined (co)polypeptides

Abstract

By associating primary (slow but controlled ring-opening polymerization; ROP) and tertiary (fast but uncontrolled ROP) amines in the same molecule, a novel highly active organocatalytic system proceeding by an accelerated amine mechanism through monomer activation (AAMMA) and leading to living ROP of α-amino acid N-carboxyanhydrides at room temperature was successfully developed.

Graphical abstract: From competition to cooperation: a highly efficient strategy towards well-defined (co)polypeptides

Supplementary files

Article information

Article type
Communication
Submitted
13 Nov 2014
Accepted
21 Jan 2015
First published
26 Jan 2015

Chem. Commun., 2015,51, 3663-3666

Author version available

From competition to cooperation: a highly efficient strategy towards well-defined (co)polypeptides

W. Zhao, Y. Gnanou and N. Hadjichristidis, Chem. Commun., 2015, 51, 3663 DOI: 10.1039/C4CC09055A

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