Presented here are two novel open-framework cobalt sulfate-oxalates constructed from molecular and chain-like building blocks. The two compounds have different structures: an hcb-type layer with 20-ring windows and a mog-type framework with 12-ring channels. Amine molecules play dual roles in the two structures: as a chelating ligand and a charge-balancing agent.
K. Wang, D. Luo, D. Xu, F. Guo, L. Liu and Z. Lin, Dalton Trans., 2014, 43, 13476 DOI: 10.1039/C4DT01503G
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