Issue 38, 2015

C–H bond functionalization based on metal carbene migratory insertion

Abstract

Cross-coupling reactions involving metal carbene migratory insertion have been established as a new type of coupling reaction with diazo compounds as the reaction partners. Since 2011, an interesting development has been made in which the carbene migratory insertion process is successfully merged into C–H bond activations. Along this line, a series of investigations have been documented in the past few years. This feature article summarizes the developments in this area.

Graphical abstract: C–H bond functionalization based on metal carbene migratory insertion

Article information

Article type
Feature Article
Submitted
18 Jan 2015
Accepted
15 Feb 2015
First published
17 Feb 2015

Chem. Commun., 2015,51, 7986-7995

Author version available

C–H bond functionalization based on metal carbene migratory insertion

F. Hu, Y. Xia, C. Ma, Y. Zhang and J. Wang, Chem. Commun., 2015, 51, 7986 DOI: 10.1039/C5CC00497G

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