Issue 46, 2015

Oxocentered Cu(ii) lead selenite honeycomb lattices hosting Cu(i)Cl2 groups obtained by chemical vapor transport reactions

Abstract

Chemical vapor transport (CVT) reactions were used to prepare three modular mixed-valent Cu(I)–Cu(II) compounds, (Pb2Cu2+9O4)(SeO3)4(Cu+Cl2)Cl5 (1), (PbCu2+5O2)(SeO3)2(Cu+Cl2)Cl3 (2), and (PbxCu2+(6−x)O2)(SeO3)2(Cu+Cl2)K(1−x)Cl(4−x) (x = 0.20) (3). In their crystal structures chains of anion-centered (OCu2+4) and (OCu2+3Pb) tetrahedra form honeycomb-like double layers with cavities occupied by linear [Cu+Cl2] groups.

Graphical abstract: Oxocentered Cu(ii) lead selenite honeycomb lattices hosting Cu(i)Cl2 groups obtained by chemical vapor transport reactions

Supplementary files

Article information

Article type
Communication
Submitted
15 Feb 2015
Accepted
30 Apr 2015
First published
01 May 2015

Chem. Commun., 2015,51, 9563-9566

Author version available

Oxocentered Cu(II) lead selenite honeycomb lattices hosting Cu(I)Cl2 groups obtained by chemical vapor transport reactions

V. M. Kovrugin, M. Colmont, O. I. Siidra, O. Mentré, A. Al-Shuray, V. V. Gurzhiy and S. V. Krivovichev, Chem. Commun., 2015, 51, 9563 DOI: 10.1039/C5CC01426C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements