Issue 65, 2015

Dinitrogen extrusion from enoldiazo compounds under thermal conditions: synthesis of donor–acceptor cyclopropenes

Abstract

Donor–acceptor cyclopropenes are formed quantitatively or in high yield from enoldiazoacetates and enoldiazoacetamides under moderate thermal conditions. They are more versatile than their corresponding enoldiazocarbonyl compounds as carbene precursors.

Graphical abstract: Dinitrogen extrusion from enoldiazo compounds under thermal conditions: synthesis of donor–acceptor cyclopropenes

Supplementary files

Article information

Article type
Communication
Submitted
17 Jun 2015
Accepted
09 Jul 2015
First published
09 Jul 2015

Chem. Commun., 2015,51, 12924-12927

Author version available

Dinitrogen extrusion from enoldiazo compounds under thermal conditions: synthesis of donor–acceptor cyclopropenes

Y. Deng, C. Jing and M. P. Doyle, Chem. Commun., 2015, 51, 12924 DOI: 10.1039/C5CC05006E

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