Issue 91, 2015
From the journal:

Chemical Communications

Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices†

Xin Wu,a   Hua-Bin Zhang,a   Zhong-Xuan Xua  and  Jian Zhang*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: zhj@fjirsm.ac.cn

Abstract

Two three-dimensional (3D) homochiral metal–organic frameworks, integrating double helical chains based on enantiopure ligands and single helical structures braided by 4,4′-bipyridine (bipy) and cadmium clusters, have been synthesized successfully, as a result of complete asymmetric induction between the two types of helix.

Graphical abstract: Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices

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Article information

DOI
https://doi.org/10.1039/C5CC06501A
Article type
Communication
Submitted
04 Aug 2015
Accepted
09 Sep 2015
First published
09 Sep 2015

Chem. Commun., 2015,51, 16331-16333

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Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices

X. Wu, H. Zhang, Z. Xu and J. Zhang, Chem. Commun., 2015, 51, 16331 DOI: 10.1039/C5CC06501A

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