Issue 90, 2015

The effect of particle size and ligand configuration on the asymmetric catalytic properties of proline-functionalized Pt-nanoparticles

Abstract

The effect of particle size on the asymmetric catalytic properties of supported ligand-functionalized nanoparticles (NPs) was investigated for the first time and found to alter significantly the activity but surprisingly not the stereoselectivity. These results suggest that the stereoselectivity of these complex systems is primarily determined by the ligand–reactant interaction, whereas the activity is determined by the particle size.

Graphical abstract: The effect of particle size and ligand configuration on the asymmetric catalytic properties of proline-functionalized Pt-nanoparticles

Supplementary files

Article information

Article type
Communication
Submitted
19 Aug 2015
Accepted
17 Sep 2015
First published
17 Sep 2015

Chem. Commun., 2015,51, 16221-16224

Author version available

The effect of particle size and ligand configuration on the asymmetric catalytic properties of proline-functionalized Pt-nanoparticles

I. Schrader, S. Neumann, R. Himstedt, A. Zana, J. Warneke and S. Kunz, Chem. Commun., 2015, 51, 16221 DOI: 10.1039/C5CC06990D

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