Issue 44, 2015

A versatile and highly efficient post-functionalization method for grafting organic molecules onto Anderson-type polyoxometalates

Abstract

A new azide functionalized Anderson polyoxometalate was synthesized, fully characterized and subsequently used as a building block for further POM post-functionalization with organic compounds through a copper catalyzed azide–alkyne cycloaddition (CuAAC) reaction. Optimization of the reaction conditions led to an efficient, fast, convenient and versatile POM coupling method.

Graphical abstract: A versatile and highly efficient post-functionalization method for grafting organic molecules onto Anderson-type polyoxometalates

Supplementary files

Article information

Article type
Communication
Submitted
11 Sep 2015
Accepted
07 Oct 2015
First published
21 Oct 2015

Dalton Trans., 2015,44, 19059-19062

A versatile and highly efficient post-functionalization method for grafting organic molecules onto Anderson-type polyoxometalates

S. Vanhaecht, J. Jacobs, L. Van Meervelt and T. N. Parac-Vogt, Dalton Trans., 2015, 44, 19059 DOI: 10.1039/C5DT03559G

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