Issue 70, 2016

The diastereoselective synthesis of octahedral cationic iridium hydride complexes with a stereogenic metal centre

Abstract

We report herein the highly diastereoselective synthesis of octahedral cationic Ir(III) hydride complexes with a stereogenic metal centre following various strategies. The configurational stability of these compounds has also been investigated.

Graphical abstract: The diastereoselective synthesis of octahedral cationic iridium hydride complexes with a stereogenic metal centre

Supplementary files

Article information

Article type
Communication
Submitted
21 Jul 2016
Accepted
02 Aug 2016
First published
02 Aug 2016

Chem. Commun., 2016,52, 10629-10631

The diastereoselective synthesis of octahedral cationic iridium hydride complexes with a stereogenic metal centre

N. Humbert and C. Mazet, Chem. Commun., 2016, 52, 10629 DOI: 10.1039/C6CC06020J

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