Contrary to recent reports, the dehydrocoupling of pinacol borane and 9-borabicyclononane with a variety of amines, alcohols and thiols can be achieved under mild conditions without catalyst. This process involves the formation of Lewis acid–base adducts featuring a hydridic B–H in close proximity to an acidic Nu–H.
E. A. Romero, J. L. Peltier, R. Jazzar and G. Bertrand, Chem. Commun., 2016, 52, 10563 DOI: 10.1039/C6CC06096J
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