Ultra-fast mechanochemical synthesis of boron phosphides, BP and B12P2

Vladimir A. Mukhanov; Dominique Vrel; Petr S. Sokolov; Yann Le Godec; Vladimir L. Solozhenko

doi:10.1039/C6DT00435K

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Ultra-fast mechanochemical synthesis of boron phosphides, BP and B₁₂P₂†

Vladimir A. Mukhanov,^a Dominique Vrel,^a Petr S. Sokolov,^a Yann Le Godec^b and Vladimir L. Solozhenko*^a

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* Corresponding authors

^a LSPM–CNRS, Université Paris Nord, 93430 Villetaneuse, France
E-mail: vladimir.solozhenko@univ-paris13.fr
Fax: +331 49 40 34 92

^b IMPMC, Université Pierre et Marie Curie, 75005 Paris, France

Abstract

Here we propose a new approach to the synthesis of single-phase boron phosphides (BP and B₁₂P₂) by mechanochemical reactions between boron phosphate and magnesium/magnesium diboride in the presence of an inert diluent (sodium chloride). The proposed method is characterized by the simplicity of implementation, high efficiency, low cost of the product, and good perspectives for large-scale production.

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Article information

DOI: https://doi.org/10.1039/C6DT00435K
Article type: Communication
Submitted: 31 Jan 2016
Accepted: 24 Feb 2016
First published: 09 May 2016

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Dalton Trans., 2016,45, 10122-10126

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Ultra-fast mechanochemical synthesis of boron phosphides, BP and B₁₂P₂

V. A. Mukhanov, D. Vrel, P. S. Sokolov, Y. Le Godec and V. L. Solozhenko, Dalton Trans., 2016, 45, 10122 DOI: 10.1039/C6DT00435K

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