Bioelectrocalorimetry allows assessing the heat (enthalpy) balance and revealing the microbial electrochemical Peltier heat of biofilm electrodes. This effect accounts for a heat formation of 27 ± 6 kJ mol−1 of electrons transferred and represents a significant energy loss for primary microbial electrochemical technologies.
B. Korth, T. Maskow, C. Picioreanu and F. Harnisch, Energy Environ. Sci., 2016, 9, 2539 DOI: 10.1039/C6EE01428C
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