Issue 28, 2016

Thiophene-based conjugated microporous polymers: preparation, porosity, exceptional carbon dioxide absorption and selectivity

Abstract

The preparation and sorption properties of thiophene-based conjugated microporous polymers (CMPs) have been reported. The BET surface area of these porous polymers varied between 622 and 911 m2 g−1, and SCMP-COOH@1 showed an excellent CO2 uptake capacity of 817 mg g−1 at 318 K under 60 bar pressure. In addition, SCMPs show good adsorption selectivity for CO2 over N2 and CH4.

Graphical abstract: Thiophene-based conjugated microporous polymers: preparation, porosity, exceptional carbon dioxide absorption and selectivity

Supplementary files

Article information

Article type
Communication
Submitted
14 Apr 2016
Accepted
06 Jun 2016
First published
15 Jun 2016

Polym. Chem., 2016,7, 4599-4602

Thiophene-based conjugated microporous polymers: preparation, porosity, exceptional carbon dioxide absorption and selectivity

L. Qin, G. Xu, C. Yao and Y. Xu, Polym. Chem., 2016, 7, 4599 DOI: 10.1039/C6PY00666C

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