Issue 17, 2017, Issue in Progress

Choline chloride–zinc chloride ionic liquid as a green template for the sol–gel synthesis of mesoporous titania

Abstract

Utilization of organic templates for the synthesis of structure- and morphology-controlled solids is being researched extensively. Use of green templates provides advantages in the form of easy processability and less toxicity compared to conventional chemical templates, in addition to customizable mesoporous network structures in solids. In this regard, the present work aimed at assessing the influence of choline chloride–zinc chloride ionic liquid (IL) in controlling the crystallite characteristics and improving the surface properties of sol–gel derived nanotitania. Thermal, surface area, porosity, crystallinity, chemical composition, textural and morphological characterizations of the IL templated titania are described in the present work. XRD results showed that all IL templated titania samples possessed anatase structure. The sample prepared using 2 mL of IL with 9 mL of titanium tetraisopropoxide (ILT-2) possessed uniformly dispersed, spherical particles with an average particle size of 13.2 nm and a surface area of 75.1 m2 g−1. A moderate red shift of the absorption profile of titania was also observed. Among the synthesized samples, ILT-2 exhibited the highest photocatalytic activity for the degradation of 4-chlorophenol under UV irradiation. The ability of the choline chloride–zinc chloride IL to offer very good control over the growth of titania particles together with its easy removal make it a potential green template for the sol–gel synthesis of mesoporous solids.

Graphical abstract: Choline chloride–zinc chloride ionic liquid as a green template for the sol–gel synthesis of mesoporous titania

Article information

Article type
Paper
Submitted
31 Jul 2016
Accepted
22 Jan 2017
First published
06 Feb 2017
This article is Open Access
Creative Commons BY license

RSC Adv., 2017,7, 10081-10091

Choline chloride–zinc chloride ionic liquid as a green template for the sol–gel synthesis of mesoporous titania

T. Preethi, M. P. Padmapriya, B. Abarna and G. R. Rajarajeswari, RSC Adv., 2017, 7, 10081 DOI: 10.1039/C6RA28478G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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