Issue 32, 2016
From the journal:

Journal of Materials Chemistry A

Visible light photocatalysis by metal-to-metal charge transfer for degradation of methyl orange†

C. P. Ireland,a   R. G. Palgrave,‡a   S. C. Bennett,b   A. W. J. Smith,b   J. H. Clark,a   J. R. Darwent,a   J. B. Claridge,a   S. Poulstonb  and  M. J. Rosseinsky*a  

* Corresponding authors

a Department of Chemistry, University of Liverpool, Liverpool, UK
E-mail: m.j.rosseinsky@liv.ac.uk
Fax: +44 (0)151 794 3587
Tel: +44 (0)151 794 3499

b Johnson Matthey Technology Centre, Blounts Court, Sonning Common, Reading RG4 9NH, UK

Abstract

We have impregnated chromium(III) onto a high surface area particulate niobium oxide to make bulk oxide–oxide interfaces, identifying by a combination of X-ray photoelectron spectroscopy and diffuse reflectance the exact energy of the metal-to-metal charge transfer transition that is responsible for the visible light photocatalytic decomposition of methyl orange.

Graphical abstract: Visible light photocatalysis by metal-to-metal charge transfer for degradation of methyl orange

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Article information

DOI
https://doi.org/10.1039/C6TA00192K
Article type
Paper
Submitted
07 Jan 2016
Accepted
08 Jul 2016
First published
08 Jul 2016

J. Mater. Chem. A, 2016,4, 12479-12486

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Visible light photocatalysis by metal-to-metal charge transfer for degradation of methyl orange

C. P. Ireland, R. G. Palgrave, S. C. Bennett, A. W. J. Smith, J. H. Clark, J. R. Darwent, J. B. Claridge, S. Poulston and M. J. Rosseinsky, J. Mater. Chem. A, 2016, 4, 12479 DOI: 10.1039/C6TA00192K

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