Issue 15, 2018

Direct oxidative isoperfluoropropylation of terminal alkenes via hexafluoropropylene (HFP) and silver fluoride

Abstract

A copper-mediated oxidative isoperfluoropropylation of unactivated terminal alkenes with commercially available hexafluoropropylene (HFP) has been developed. With operational simplicity of the procedure and broad substrate applicability, this strategy provides a general and straightforward way for the construction of C(sp3)–C3F7-i bonds. A variety of allylic isoperfluoropropylated compounds have been efficiently synthesized using this strategy.

Graphical abstract: Direct oxidative isoperfluoropropylation of terminal alkenes via hexafluoropropylene (HFP) and silver fluoride

Supplementary files

Article information

Article type
Communication
Submitted
09 Oct 2017
Accepted
19 Jan 2018
First published
19 Jan 2018

Chem. Commun., 2018,54, 1877-1880

Direct oxidative isoperfluoropropylation of terminal alkenes via hexafluoropropylene (HFP) and silver fluoride

X. Wang and Y. Wu, Chem. Commun., 2018, 54, 1877 DOI: 10.1039/C7CC07614B

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