Enhancement of metal–metal interactions inside a large-cavity synthetic host in water

Shengjian Kuang; Zhixiong Hu; Hao Zhang; Xiongzhi Zhang; Feng Liang; Zhiyong Zhao; Simin Liu

doi:10.1039/C8CC00593A

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Enhancement of metal–metal interactions inside a large-cavity synthetic host in water†

Shengjian Kuang,^a Zhixiong Hu,^a Hao Zhang,^a Xiongzhi Zhang,^a Feng Liang,

^a Zhiyong Zhao^a and Simin Liu

*^a

Author affiliations

* Corresponding authors

^a The State Key Laboratory of Refractories and Metallurgy, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
E-mail: liusimin@wust.edu.cn

Abstract

The encapsulation of a series of metal–terpyridyl complexes in cucurbit[10]uril (CB[10]) in water is described. A strong enhancement of metal–metal and π–π interactions is observed due to double confinement in the large cavity. Furthermore, a linear supramolecular polymer featuring host-enhanced metallophilic interactions in water can be prepared.

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DOI: https://doi.org/10.1039/C8CC00593A
Article type: Communication
Submitted: 24 Jan 2018
Accepted: 02 Feb 2018
First published: 02 Feb 2018

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Chem. Commun., 2018,54, 2169-2172

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Enhancement of metal–metal interactions inside a large-cavity synthetic host in water

S. Kuang, Z. Hu, H. Zhang, X. Zhang, F. Liang, Z. Zhao and S. Liu, Chem. Commun., 2018, 54, 2169 DOI: 10.1039/C8CC00593A

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Chemical Communications

Enhancement of metal–metal interactions inside a large-cavity synthetic host in water†

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Enhancement of metal–metal interactions inside a large-cavity synthetic host in water

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