Issue 85, 2018
From the journal:

Chemical Communications

A new strategy for constructing a disulfide-functionalized ZIF-8 analogue using structure-directing ligand–ligand covalent interaction†

Yanli Gai,ab   Xitong Chen, ORCID logo b   Huajun Yang, ORCID logo c   Yanxiang Wang,b   Xianhui Bu ORCID logo *c  and  Pingyun Feng ORCID logo *b  

* Corresponding authors

a School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu 221116, P. R. China

b Department of Chemistry, University of California, Riverside, California 92521, USA
E-mail: pingyun.feng@ucr.edu

c Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Boulevard, Long Beach, California 90840, USA
E-mail: xianhui.bu@csulb.edu

Abstract

Inter-ligand van der Waals forces play a key role in the synthesis of different ZIF types. Here we report an unusual case involving covalent inter-ligand interactions through disulfide bond formation in a ZIF-8 analogue. It exhibits high CO2 uptake and stepwise adsorption of light hydrocarbons with potential applications in ethane/ethylene separation.

Graphical abstract: A new strategy for constructing a disulfide-functionalized ZIF-8 analogue using structure-directing ligand–ligand covalent interaction

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Article information

DOI
https://doi.org/10.1039/C8CC07064D
Article type
Communication
Submitted
30 Aug 2018
Accepted
01 Oct 2018
First published
10 Oct 2018

Chem. Commun., 2018,54, 12109-12112

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A new strategy for constructing a disulfide-functionalized ZIF-8 analogue using structure-directing ligand–ligand covalent interaction

Y. Gai, X. Chen, H. Yang, Y. Wang, X. Bu and P. Feng, Chem. Commun., 2018, 54, 12109 DOI: 10.1039/C8CC07064D

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