Issue 9, 2019

Rhodium(iii)-catalyzed aromatic C–H cyanation with dimethylmalononitrile as a cyanating agent

Abstract

A rhodium-catalyzed aromatic C–H bond direct cyanation with safe, bench-stable, and commercially available dimethylmalononitrile as the cyanating agent has been successfully developed by using copper oxide as a promotor. Pyridine, quinoline, pyrimidine and pyrazole were used as the directing group in this type of C–H bond direct cyanation reaction.

Graphical abstract: Rhodium(iii)-catalyzed aromatic C–H cyanation with dimethylmalononitrile as a cyanating agent

Supplementary files

Article information

Article type
Communication
Submitted
12 Nov 2018
Accepted
10 Dec 2018
First published
10 Dec 2018

Chem. Commun., 2019,55, 1209-1212

Rhodium(III)-catalyzed aromatic C–H cyanation with dimethylmalononitrile as a cyanating agent

H. Li, S. Zhang, X. Yu, X. Feng, Y. Yamamoto and M. Bao, Chem. Commun., 2019, 55, 1209 DOI: 10.1039/C8CC08930B

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