A disk-type polyarene containing four B←N units

Yang Min; Chuandong Dou; Hongkun Tian; Jun Liu; Lixiang Wang

doi:10.1039/C9CC00769E

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A disk-type polyarene containing four B←N units†

Yang Min,^ab Chuandong Dou,*^a Hongkun Tian,^a Jun Liu

*^a and Lixiang Wang

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* Corresponding authors

^a State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, People's Republic of China
E-mail: chuandong.dou@ciac.ac.cn, liujun@ciac.ac.cn

^b University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China

Abstract

In this manuscript, we report a disk-type polyarene consisting of an all-hexagon π-framework and four B←N units. It exhibits intriguing electronic structures and opto-electronic properties, such as locally modulated (anti)aromaticity, strong red fluorescence and n-type semiconductor characteristics, thus representing a new kind of π-molecule containing B←N units.

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DOI: https://doi.org/10.1039/C9CC00769E
Article type: Communication
Submitted: 28 Jan 2019
Accepted: 28 Feb 2019
First published: 01 Mar 2019

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Chem. Commun., 2019,55, 3638-3641

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A disk-type polyarene containing four B←N units

Y. Min, C. Dou, H. Tian, J. Liu and L. Wang, Chem. Commun., 2019, 55, 3638 DOI: 10.1039/C9CC00769E

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Chemical Communications

A disk-type polyarene containing four B←N units†

Abstract

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A disk-type polyarene containing four B←N units

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