Issue 48, 2019

Allylation of aldehydes by dual photoredox and nickel catalysis

Abstract

Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. The process utilizes the combination of a Ni(II) complex, [Ru(bpy)3]2+ as a photoredox catalyst, and allylacetate under blue LED irradiation, and allows the synthesis of a large variety of homoallylic alcohols.

Graphical abstract: Allylation of aldehydes by dual photoredox and nickel catalysis

Supplementary files

Article information

Article type
Communication
Submitted
30 Apr 2019
Accepted
02 May 2019
First published
03 May 2019

Chem. Commun., 2019,55, 6838-6841

Allylation of aldehydes by dual photoredox and nickel catalysis

A. Gualandi, G. Rodeghiero, A. Faraone, F. Patuzzo, M. Marchini, F. Calogero, R. Perciaccante, T. P. Jansen, P. Ceroni and P. G. Cozzi, Chem. Commun., 2019, 55, 6838 DOI: 10.1039/C9CC03344K

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