Issue 22, 2019
From the journal:

Dalton Transactions

Five new 3D transition MOFs based on 1-(3,5-dicarboxylatobenzyl)-3,5-pyrazole dicarboxylic acid displaying unique luminescence sensing towards Fe3+ and magnetic properties†

Wei-Ni Liu,‡a   Wen-Quan Tong,‡a   Lu-Lu Ma,a   Yao Wang,a   Jiao-Min Wang,a   Lei Hou ORCID logo *a  and  Yao-Yu Wang ORCID logo *a  

* Corresponding authors

a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China
E-mail: wyaoyu@nwu.edu.cn, lhou2009@nwu.edu.cn

Abstract

Five new 3D MOFs: {[Zn3(HL)2H2O]·4H2O}n (1), {[Ba2L5H2O]·2H2O}n (2), {[Ba4(L)2·5H2O]·2H2O}n (3), {[Cd3(HL)2·Cl2·2H2O]·2H2O}n (4) and {[Cu2(L)2·2H2O]·4H2O}n (5), were constructed based on 1-(3,5-dicarboxylatobenzyl)-3,5-pyrazole dicarboxylic acid. Structural analysis shows that 1–5 have 3D frameworks, among which 1(Zn) exhibits high luminescence sensing for Fe3+ ions, excellent framework stability and reusability. The sensing mechanism of 1(Zn) is briefly discussed. In addition, 5(Cu) displays antiferromagnetic exchange phenomena.

Graphical abstract: Five new 3D transition MOFs based on 1-(3,5-dicarboxylatobenzyl)-3,5-pyrazole dicarboxylic acid displaying unique luminescence sensing towards Fe3+ and magnetic properties

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9DT00933G
Article type
Paper
Submitted
02 Mar 2019
Accepted
09 Apr 2019
First published
10 Apr 2019

Dalton Trans., 2019,48, 7786-7793

Permissions

Request permissions

Five new 3D transition MOFs based on 1-(3,5-dicarboxylatobenzyl)-3,5-pyrazole dicarboxylic acid displaying unique luminescence sensing towards Fe3+ and magnetic properties

W. Liu, W. Tong, L. Ma, Y. Wang, J. Wang, L. Hou and Y. Wang, Dalton Trans., 2019, 48, 7786 DOI: 10.1039/C9DT00933G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements