Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand

Changguang Yao; Tonghuan Zhang; Chunhui Zhou; Kuo-Wei Huang

doi:10.1039/C9DT03003D

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Interrogating the steric outcome during H₂ heterolysis: in-plane steric effects in the regioselective protonation of the PN³P-pincer ligand†

Changguang Yao,^a Tonghuan Zhang,^ab Chunhui Zhou^a and Kuo-Wei Huang

*^a

Author affiliations

* Corresponding authors

^a KAUST Catalysis Center and Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia
E-mail: hkw@kaust.edu.sa

^b Lab of Computational Chemistry and Drug Design, State Key Laboratory of Chemical Oncogenomics, Peking University Shenzhen Graduate School, Shenzhen 518055, China

Abstract

H₂ heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2^nd generation PN³P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H₂ splitting process.

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Article information

DOI: https://doi.org/10.1039/C9DT03003D
Article type: Communication
Submitted: 22 Jul 2019
Accepted: 02 Aug 2019
First published: 05 Aug 2019
This article is Open Access

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Dalton Trans., 2019,48, 12817-12821

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Interrogating the steric outcome during H₂ heterolysis: in-plane steric effects in the regioselective protonation of the PN³P-pincer ligand

C. Yao, T. Zhang, C. Zhou and K. Huang, Dalton Trans., 2019, 48, 12817 DOI: 10.1039/C9DT03003D

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