SCHEDULED MAINTENANCE
Photoinduced electron transfer in a non-covalent assembly based on supramolecular contacts between the phenolic hydroxy groups of a calix[4]arene-substituted ZnII metalloporphyrin photodonor and the carbonyl groups of a benzoquinone acceptor (Ka= 40 ± 3.6 dm3 mol–1) in CDCl3 occurs with a rate constant of (8.0 ± 0.2)× 108 s–1.
T. Arimura, C. T. Brown, S. L. Springs and J. L. Sessler, Chem. Commun., 1996, 2293 DOI: 10.1039/CC9960002293
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