Issue 31, 2020

Quantifying the nitrogen effect on CO2 capture using isoporous network polymers

Abstract

The impact of nitrogen atoms on CO2 binding was evaluated for two isostructural porous bisimidazole-linked polymers (BILPs), which serendipitously had identical surface areas and pore size distributions, a very rare observation. The two structures differ only in the core of the trialdehyde component, the nitrogen atom (BILP-19) versus benzene ring (BILP-5). Such a slight difference, however, has brought about a stronger CO2 capture capacity of BILP-19 and hence increased CO2/N2 separation capability.

Graphical abstract: Quantifying the nitrogen effect on CO2 capture using isoporous network polymers

Supplementary files

Article information

Article type
Communication
Submitted
07 Feb 2020
Accepted
18 Mar 2020
First published
19 Mar 2020

Chem. Commun., 2020,56, 4273-4275

Quantifying the nitrogen effect on CO2 capture using isoporous network polymers

T. S. Nguyen and C. T. Yavuz, Chem. Commun., 2020, 56, 4273 DOI: 10.1039/D0CC00982B

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