Reversing Lewis acidity from bismuth to antimony

Abstract

Investigations on the boundaries between the neutral and cationic models of (Mesityl)₂EX (E = Sb, Bi and X = Cl⁻, OTf⁻) have facilitated reversing the Lewis acidity from bismuth to antimony. We use this concept to demonstrate a higher efficiency of (Mesityl)₂SbOTf over (Mesityl)₂BiOTf in the catalytic reduction of phosphine oxides to phosphines. The experiments supported with computations described herein will find use in designing new Lewis acids relevant to catalysis.