Urchin-like hierarchical ruthenium cobalt oxide nanosheets on Ti3C2Tx MXene as a binder-free bifunctional electrode for overall water splitting and supercapacitors

Abstract

Synthesizing efficient electrode materials for water splitting and supercapacitors is essential for developing clean electrochemical energy conversion/storage devices. In the present work, we report the construction of a ruthenium cobalt oxide (RuCo₂O₄)/Ti₃C₂T_x MXene hybrid by electrophoretic deposition of Ti₃C₂T_x MXene on nickel foam (NF) followed by RuCo₂O₄ nanostructure growth through an electrodeposition process. Owing to the strong interactions between RuCo₂O₄ and Ti₃C₂T_x sheets, which are verified by density functional theory (DFT)-based simulations, RuCo₂O₄/Ti₃C₂T_x MXene@NF can serve as a bifunctional electrode for both water splitting and supercapacitor applications. This electrode exhibits outstanding electrocatalytic activity with low overpotentials of 170 and 68 mV at 100 A m⁻² toward the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). The RuCo₂O₄/Ti₃C₂T_x MXene@NF-based alkaline water-splitting cell only requires 1.62 V to achieve a current density of 100 A m⁻², which is much better than that of RuO₂@NF and Pt/C@NF-assembled cells (1.75 V@100 A m⁻²). The symmetric supercapacitor (SSC)-assembled electrode displays a high specific capacitance of 229 F g⁻¹ at 3 A g⁻¹. The experimental results, complemented with theoretical insights, provide an effective strategy to prepare multifunctional materials for electrocatalysis and energy storage applications.