Issue 43, 2021
From the journal:

RSC Advances

Evaluation of P-bridged biaryl phosphine ligands in palladium-catalysed Suzuki–Miyaura cross-coupling reactions†‡

Jairus L. Lamola, ORCID logo a   Paseka T. Moshapo,a   Cedric W. Holzapfel§a  and  Munaka Christopher Maumela*ab  

* Corresponding authors

a Research Centre for Synthesis and Catalysis, Department of Chemical Sciences University of Johannesburg, Kingsway Campus, Auckland Park 2006, South Africa
E-mail: chris.maumela@sasol.com

b Sasol (Pty) Ltd, Research and Technology (R & T), 1 Klasie Havenga Rd, Sasolburg 1947, South Africa
E-mail: chris.maumela@sasol.com

Abstract

A family of biaryl phosphacyclic ligands derived from phobane and phosphatrioxa-adamantane frameworks is described. The rigid biaryl phosphacycles are efficient for Suzuki–Miyaura cross-coupling of aryl bromides and chlorides. In particular, coupling reactions of the challenging sterically hindered and heterocyclic substrates were viable at room temperature.

Graphical abstract: Evaluation of P-bridged biaryl phosphine ligands in palladium-catalysed Suzuki–Miyaura cross-coupling reactions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1RA04947J
Article type
Paper
Submitted
25 Jun 2021
Accepted
18 Jul 2021
First published
05 Aug 2021
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2021,11, 26883-26891

Permissions

Request permissions

Evaluation of P-bridged biaryl phosphine ligands in palladium-catalysed Suzuki–Miyaura cross-coupling reactions

J. L. Lamola, P. T. Moshapo, C. W. Holzapfel and M. C. Maumela, RSC Adv., 2021, 11, 26883 DOI: 10.1039/D1RA04947J

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements