An amphoteric betaine electrolyte additive enabling a stable Zn metal anode for aqueous batteries

Abstract

The corrosion and dendritic growth of the Zn anode limit its electrochemical performance in aqueous Zn batteries. Here, we present an amphoteric betaine additive for 5 m ZnCl₂ aqueous electrolyte. The carboxyl group on betaine forms hydrogen bonds with water and reduces the water activity. The molecule also experiences preferential adsorption on the Zn surface and separates the interactions between Zn and water. Side reactions at the Zn electrode are thus inhibited. The regulated interface also ensures uniform Zn deposition. As a result, the electrolyte with betaine additive allows reversible Zn plating/stripping for over 1400 h at 0.5 mA cm⁻². A capacity retention of 94% is obtained after 3000 cycles for a VO₂ cathode.