Hollow CoS2 anchored on hierarchically porous carbon derived from Pien Tze Huang for high-performance supercapacitors

Abstract

The development of electrode materials with a high specific capacitance, power density, and long-term stability is essential and remains a challenge for developing supercapacitors. Cobalt sulfides (CoS₂) are considered one of the most promising and widely studied electrode materials for supercapacitors. Herein, CoS₂ and hierarchical porous carbon derived from Pien Tze Huang waste are assembled into a cobalt sulfide/carbon (CoS₂/PZH) matrix composite using a one-step hydrothermal method to resolve the challenges of supercapacitors. The resulting CoS₂/PZH composite material exhibits a hierarchical porous structure with hollow CoS₂ embedded in a PZH framework. The uniform dispersion of the hierarchical porous structure CoS₂/PZH is achieved due to the PZH framework, while the uniform decoration of the porous PZH with the hollow CoS₂ prevents the PZH from stacking easily. Moreover, the excellent synergistic effect of the hierarchical porous and hollow structure of CoS₂/PZH can shorten the electron/ion diffusion channels, expose additional active sites, and provide stable structures for subsequent reactions. As a result, the CoS₂/PZH composite material displays a high initial specific capacity of 447.5 F g⁻¹ at 0.5 A g⁻¹, a high energy density of 22.38 W h kg⁻¹, and long-term cycling stability (a retention rate of 92.3% over 10 000 cycles at 5 A g⁻¹).