Photobase-catalysed anionic thiol-epoxy click photopolymerization under NIR irradiation: from deep curing to shape memory

Yaoxin Huang; Longji Li; Xiaoxuan Liu; Zhiquan Li

doi:10.1039/D2PY00144F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Photobase-catalysed anionic thiol-epoxy click photopolymerization under NIR irradiation: from deep curing to shape memory†

Yaoxin Huang,^a Longji Li,^a Xiaoxuan Liu

^ab and Zhiquan Li

*^ab

Author affiliations

* Corresponding authors

^a School of Materials and Energy, Guangdong University of Technology, Guangzhou, Guangdong, China
E-mail: lzq@gdut.edu.cn

^b Guangdong Laboratory of Chemistry and Fine Chemical Industry Jieyang Center, Guangdong Province, PR China

Abstract

Several unimolecular photobase generators capable of catalyzing upconversion nanoparticle-assisted anionic thiol-epoxy click photopolymerization are presented. The fabricated polymers, with a curing depth of 11.8 cm, are dual-wavelength responsive and display shape memory function, showing great potential for the construction of smart medical devices and robots.

This article is part of the themed collection: Photopolymer science

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D2PY00144F
Article type: Communication
Submitted: 31 Jan 2022
Accepted: 01 Apr 2022
First published: 04 Apr 2022

Download Citation

Polym. Chem., 2022,13, 3048-3052

Permissions

Request permissions

Photobase-catalysed anionic thiol-epoxy click photopolymerization under NIR irradiation: from deep curing to shape memory

Y. Huang, L. Li, X. Liu and Z. Li, Polym. Chem., 2022, 13, 3048 DOI: 10.1039/D2PY00144F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Polymer Chemistry

Photobase-catalysed anionic thiol-epoxy click photopolymerization under NIR irradiation: from deep curing to shape memory†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Photobase-catalysed anionic thiol-epoxy click photopolymerization under NIR irradiation: from deep curing to shape memory

Social activity

Search articles by author

Spotlight

Advertisements