Nanoscale carbon dot-embedded metal–organic framework for turn-on fluorescence detection of water in organic solvents

Abstract

An easy-to-use, highly selective, and real-time organic solvent quality assessment is desirable to detect water contamination in organic solvents. Herein, a one-step procedure using ultrasound irradiation was used for encapsulating nanoscale carbon dots (CDs) into metal–organic framework-199 (HKUST-1) to form CDs@HKUST-1 composite. The CDs@HKUST-1 exhibited very weak fluorescence due to photo-induced electron transfer (PET) from the CDs to the Cu²⁺ centers, acting as a fluorescent sensor in its off-state. The designed material can detect and discriminate water from other organic solvents, driven by turn-on fluorescence. This highly sensitive sensing platform could be applied for the detection of water in ethanol, acetonitrile, and acetone with wide linear detection ranges of 0–70% v/v, 2–12% v/v, and 10–50% v/v and limits of detection of 0.70% v/v, 0.59% v/v, and 1.08% v/v, respectively. The detection mechanism is attributed to the interruption of the PET process due to the release of fluorescent CDs after treatment with water. A smartphone-based quantitative test was successfully developed to monitor the water content in organic solvents utilizing CDs@HKUST-1 and a phone color processing application, thus making it possible to develop an on-site, real time and easy-to-use sensor for water detection.