SCHEDULED MAINTENANCE
Computational evidence is reported for a reversal in the type of an electron transfer (ET) mechanism, induced by an intramolecular linkage of the donor (amine) and acceptor (cation radical) moieties via a single –CH2– spacer. An isotope effect probe is suggested to detect this mechanistic changeover.
A. C. Reddy, G. N. Sastry and S. Shaik, J. Chem. Soc., Perkin Trans. 2, 1995, 1717 DOI: 10.1039/P29950001717
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