The polymeric silver(I)–thiolate complex [{Ag8(µ4-SC2H4- NH3)6Cl6}Cl2]n has been prepared from the assembling reaction of silver chloride and 2-mercaptoethylamine hydrochloride in DMF; X-ray diffraction analysis shows the complex has a one dimensional chain structure and all the sulfur atoms of the thiolates exhibit µ4 bonding bridging four silver(I) centers.
W. Su, R. Cao, J. Chen and J. Lu, Chem. Commun., 1998, 1389 DOI: 10.1039/A802286K
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