Issue 2, 1999

Kinetic Isotope Effects in the Chromium(VI) Oxidation of Bicyclic Alcohols

Abstract

Pseudo first-order rate constants are determined for the oxidation of a series of secondary alcohols and their monodeutero analogues by ammonium chromate in aqueous acidic solution at several temperatures; the relative rates and activation parameters are consistent with a cyclic, symmetrical transition state.

Article information

Article type
Paper

J. Chem. Res. (S), 1999, 146-147

Kinetic Isotope Effects in the Chromium(VI) Oxidation of Bicyclic Alcohols

J. Hodge Markgraf, J. S. Dubow, J. A. Charland and E. H. Sohn, J. Chem. Res. (S), 1999, 146 DOI: 10.1039/A808311H

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