Issue 13, 1999
From the journal:

Chemical Communications

Synthesis of organometallic solids by protonation of Cp*M(CN)3n– (M = Rh, Ir, Ru)

Stephen M. Contakes,   Michael Schmidt  and  Thomas B. Rauchfuss  

Abstract

Protonation of aqueous acetone solutions of [Cp*Ir(CN)3]– produces the two-dimensional organometallic solid (H3O)-[Cp*Ir(CN)3].Me2CO wherein 14 Å diameter channels (Ir4C8N8O4) contain exchangeable solvent molecules; the analogous Ru and Rh tricyanide complexes are also susceptible to proton-induced polymerization.

About
Cited by
Related
Download options Please wait...

Additions and corrections

Article information

DOI
https://doi.org/10.1039/A902115I
Article type
Paper

Chem. Commun., 1999, 1183-1184

Permissions

Request permissions

Synthesis of organometallic solids by protonation of Cp*M(CN)3n– (M = Rh, Ir, Ru)

S. M. Contakes, M. Schmidt and T. B. Rauchfuss, Chem. Commun., 1999, 1183 DOI: 10.1039/A902115I

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements