Issue 3, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Rhenium catalysed epoxidations with hydrogen peroxide: tertiary arsines as effective cocatalysts

Michiel C. A. van Vliet,a   Isabel W. C. E. Arendsa  and  Roger A. Sheldon*a  

* Corresponding authors

a Laboratory for Organic Chemistry and Catalysis, Delft University of Technology, Julianalaan 136, Delft, The Netherlands
E-mail: secretariat-ock@stm.tudelft.nl

Abstract

Perrhenic acid in combination with tertiary arsines gives a versatile catalytic system for epoxidation of alkenes with hydrogen peroxide. The best results are obtained with diphenylmethylarsine. A wide range of alkenes could be epoxidised with aqueous hydrogen peroxide (60%) in 60–100% yields with substrate to catalyst ratios of up to 1000.

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Article information

DOI
https://doi.org/10.1039/A907975K
Article type
Paper
Submitted
04 Oct 1999
Accepted
29 Nov 1999
First published
25 Jan 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 377-380

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Rhenium catalysed epoxidations with hydrogen peroxide: tertiary arsines as effective cocatalysts

M. C. A. van Vliet, I. W. C. E. Arends and R. A. Sheldon, J. Chem. Soc., Perkin Trans. 1, 2000, 377 DOI: 10.1039/A907975K

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