Transition metal complexes of the weakly coordinating carborane anion [CB11H12]−: the first isolation and structural characterisation of an intermediate in a silver salt metathesis reaction

Nathan J. Patmore; Jonathan W. Steed; Andrew S. Weller

doi:10.1039/B002585M

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Transition metal complexes of the weakly coordinating carborane anion [CB₁₁H₁₂]⁻: the first isolation and structural characterisation of an intermediate in a silver salt metathesis reaction

Nathan J. Patmore,^a Jonathan W. Steed^b and Andrew S. Weller*^a

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* Corresponding authors

^a Department of Chemistry, University of Bath, Bath, UK
E-mail: a.s.weller@bath.ac.uk

^b Department of Chemistry, Kings College London, The Strand, London, UK

Abstract

Reaction between CpMo(CO)₃I and Ag[CB₁₁H₁₂] eventually affords CpMo(CO)₃(η¹-CB₁₁H₁₂), via the dimeric compound [CpMo(CO)₃I·Ag{CB₁₁H₁₂}] ₂ which represents the first structurally characterised intermediate in a silver salt metathesis reaction.

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Supplementary files

Crystal structure data TXT (39K)

Additions and corrections

Correction HTM (3K)

Article information

DOI: https://doi.org/10.1039/B002585M
Article type: Communication
Submitted: 31 Mar 2000
Accepted: 08 May 2000
First published: 26 May 2000

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Chem. Commun., 2000, 1055-1056

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Transition metal complexes of the weakly coordinating carborane anion [CB₁₁H₁₂]⁻: the first isolation and structural characterisation of an intermediate in a silver salt metathesis reaction

N. J. Patmore, J. W. Steed and A. S. Weller, Chem. Commun., 2000, 1055 DOI: 10.1039/B002585M

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Chemical Communications

Transition metal complexes of the weakly coordinating carborane anion [CB₁₁H₁₂]⁻: the first isolation and structural characterisation of an intermediate in a silver salt metathesis reaction

Abstract

Supplementary files

Additions and corrections

Article information

Download Citation

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Transition metal complexes of the weakly coordinating carborane anion [CB₁₁H₁₂]⁻: the first isolation and structural characterisation of an intermediate in a silver salt metathesis reaction

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