Issue 2, 2001

A remarkable Cr(iii) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion

Abstract

In addition to a quadruply bonded dichromium(II,II) compound of unusual structure, we have obtained a dinuclear, antiferromagnetically coupled, CrIII complex [Cr2(μ-OMe)23-N,C,N′ -H2DpyF)2Cl2·MeOH, H2DpyF = CH(NH-pyridyl)2] containing a transformed formamidinate group in which the central carbon atom has changed from sp2 to sp3 hybridization and Cr–C bonds have been formed; details of the crystal structure of the organometallic compound are given here.

Supplementary files

Article information

Article type
Communication
Submitted
11 Aug 2000
Accepted
06 Dec 2000
First published
09 Jan 2001

Chem. Commun., 2001, 205-206

A remarkable Cr(III) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion

R. Clérac, F. A. Cotton, C. A. Murillo and X. Wang, Chem. Commun., 2001, 205 DOI: 10.1039/B007813L

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